European Society for Quantum Solar Energy Conversion
European Conference on Organic Solar Cells
Cadarache, France, December 3-5, 1998
The Conference was organised by EUROSCI the
European Organic Solar Cell Initiative
formed in a project financed by the European Comission under the guidance of
EUREC-AGENCY, Leuven, Belgium.
Chairman's Message
Organic solar cells may provide a cheap and in several aspects unique alternative
to inorganic photovoltaics. Dye sensitized solar cells are already on the verge of
industrial production. In addition, they have also stimulated further investigations of
pure organic solid state cells as well as new cell structures such as interpenetrating
networks. Since these new approaches are highly interdisciplinary, this conference
will bring together scientists from different fields in order to provide a review of the
state of the art of this emerging technology. We also need to exchange ideas on
unconventional strategies in order to solve one of the key problems of our world, the
utilization of solar energy.
Dieter Meissner
List of Contributions
Large Area Flexible Photocells from Fullerene - Conjugated Polymer-Blends
Christoph J. Brabec, N. Serdar Sariciftci
CD Laboratory for Plastic Solar Cells, J. Kepler University, Linz, Austria
Electrical Properties in the Dark and under Illumination of Polythiophene-Based
Schottky Junctions
Nadia Camaioni, G. Casalbori-Miceli, G. Breggiato, A. Geri, M. Cristani
Instituto die Fotochimica e Radiazioni d'Alta Energi, CNR-FRAE, Bologna, Italy
Towards an all Thin Film Hybrid Organic Inorganic Solar Cell
Pierre Chartier, Hoan Nguyen Cong
Faculté de Chimie, Université Louis Pasteur, Strasbourg, France
Photoexcited Spins In Polymer / Fullerene Photo - Active Layers
Vladimir Dyakonov (1), Jürgen Parisi (1), Christoph Brabec (2),
N. Serdar Sariciftci (2), Rene A. J. Janssen (3), Jan C. Hummelen (4)
(1) Energy and Semiconductor Research, University of Oldenburg, Germany
(2) CD Laboratory for Plastic Solar Cells, J. Kepler University, Linz,
Austria
(3) Organic Chemistry, TU Eindhoven, The Netherlands
(4) Org. and Molec. Inorg Chemistry, University of Groningen, The Netherlands
Photovoltaic Effect in PPV / C60 Heterostructures and Blend Systems
Stefan Forero, Thomas Stuebinger, Karlheinz Feldrapp, Wolfgang Bruetting,
Markus Schwoerer
Experimentalphysik II, University of Bayreuth, Germany
Analytical Study of PPV - Oligomer- and C60 Based Devices for Optimizing
Organic Solar Cells
Wim Geens (1), Jef Poortmans (1), Suresh C. Jain (1), Johan Nijs (1),
Robert Mertens (1), Sjoerd C. Veenstra (2), Viktor V. Krasnikov (2), Georges
Hadziioannou (2) (1) IMEC, Leuven, The Netherlands
(2) Dpt. of Polymer Chemistry, University of Groningen, The Netherlands
Sensitization of TiO2 with p-Type Semiconductor Polymers
Albert Goossens, Barbara van der Zanden, Joop Schoonman
Interfaculty Res. Center: Renewable Energy, Delft University of Technology,
The Netherlands
The Photovoltaic Cells Based on the Nanocomposites of Conductive Polymers,
Semiconductor CdS Particles and Fullerene Layers
D. Yu. Godovsky (1), A. V. Varfolomeev (1), D. F. Zaretsky (1), A. V. Volkov (2),
A. Kundig (3), W. Caseri (3)
(1) RRC "Kurchatov Institute, Moscow, Russia (2) Chemistry Department,
Moscow State Unversity, Russia (3) ETH Zuerich, Switzerland
Photoinduced Electron Transfer from Conjugated Polymers onto Nanocrystalline
TiO2
René A. J. Janssen (1), Paul. A. van Hal (1), Martijn M. Wienk
(2), Jan M. Kroon (2)
(1) Lab. for Macromol. and Org. Chemistry, Eindhoven University of
Technology, The Netherlands
(2) ECN, Petten, The Netherlands
Photovoltaic Devices Based on Ladder Type Polyparaphenylene and a New
Perylene Containing Oligomers
G. Meinhardt (1), W. Graupner (1), G. Freistritzer (1), G. Leising
(1), K. Müllen (2)
(1) Solid State Physics, Technical University of Graz, Austria
(2) MPI for Polymer Research, Mainz, Germany
Porphyrine - Quinone Systems in Langmuir-Blodgett Films - Photoinduced
Inter- and Intramolecular Electron Transfer
Beate Röder (1), Olof Korth (1), Thomas Hanke (1), Jörg von
Gersdorff (2), Harry Kurreck (2)
(1) Institute of Physics, Humboldt University, Berlin, Germany
(2) Institute of Organic Chemistry, Humboldt University, Berlin, Germany
Demonstration of Antenna-Effect in Porphyrin Sensitized Solar Cell
Tjeerd Schaafsma, Rob Koehorst, Harry Donker
Dpt. of Biomolecular Sciences, Wageningen Agricultural University,
The Netherlands
Photovoltaic Properties of Poly-Para-Phenylene - Vinylene - Polyaniline
Blends and Influence of Encapsulation on the Photooxidation
Raoul Schröder (1), G. Freistritzer (1), W. Graupner (1), Peter
Preishuber-Pflügl (2), D. Faiman (2), F. Stelzer (3), B. Weßling
(4), G. Leising (1)
(1) Solid State Physics, Technical University of Graz, Austria
(2) Inst. for Chemic. Technol. of Inorg. Compounds, Technical University
of Graz, Austria
(3) National Solar Energy Center, Ben-Gurion University, Sede Boquer, Israel
(4) Ormecon Chemie, Ammersbek, Germany
Determination of the Quantum Efficiency of Charge Separation in an lnorganic
Semiconductor / Conducting Polymer Bilayer using the Time-Resolved Microwave
Conductivity Technique (TRMC)
Tom Savenije, Martien J. W. Vermeulen, Matthijs P. de Haas, John M. Warman
Radiation Chemistry Dpt., Delft University of Technology, The Netherlands
A New Class of Processable Low Band Gap Polymers: Interesting Materials
for Organic Solar Cells ?
Dirk Vangeneugden, Ralf Kiebooms, Dirk Vanderzande, Jan Gelan
Inst. for Materials Research, Limburg University, Belgium
Crystal Formation in Conjugated Polymer / Dye Blend Photovoltaic Cells
J. J. Dittmer (1), R. Lazzaroni (2), Ph. Leclère (2), P. Moretti (2), J.-L.
Bredas (2), Klaus Petritsch (1), M. Granström (1), A. Marseglia (1), R. H. Friend
(1)
(1) Cavendish Laboratory, University of Cambridge, UK
(2) Centre de Chimie des Matériaux Nouveau, University of
Mons-Hainaut, Belgium
Design and Stability Aspects of Dye Sensitized Solar Cells
A. Hinsch, J. Kroon, J. Wienke, J. A. M. van Roosmalen
ECN, Petten, The Netherlands
A Single Layer Liquid Crystalline Photovoltaic Cell
Klaus Petritsch (1), Richard H. Friend (1), A. Lux (2), G. G. Rozenberg
(2), S. C. Moratti (2), A. B. Holmes (2)
(1) Cavendish Laboratory, University of Cambridge, UK
(2) Melville Lab. for Polymer Synthesis, Cambridge, UK
Controlled Doping of Organic Dyes: Basic Mechanisms and Application in
Diodes and Solar Cells
M. Pfeiffer, A. Beyer, J. Blochwitz, M. Hoffmann, A. Nollau, T. Fritz,
K. Leo
Inst. for Applied Photophysics, Technical University of Dresden, Germany
Long-Term Stability of Nanocrystalline Dye-Sensitized Solar
Cells
J. M. Kroon (1), E. Rijnberg (1), J. Wienke (1), A. Hinsch (1), J.
A. M. van Roosmalen (1), W. C. Sinke (1), B. J. R. Scholtens (2), J. G. de
Vries (2), C. G. de Koster (2), A. L. L. Duchateau (2), I. C. H. Maes (2),
H. J. W. Henderickx (2)
(1) ECN Solar and Wind Energy, Petten, The Netherlands
(2) DSM Research, Geleen, The Netherlands
The Status of Molecular Organic Solar Cells as Investigated in the EUROSCI
Project
Giampiero Ruani (1), Jean-Michel Nunzi (2), Carlo Tagliani (1), Paul
Lane (3), Donal Bradley (3), Christine Videlot (4), Denis Fichou (4), Jörn
Rostalski (5) and Dieter Meissner (5)
(1) ISM, CNR Bologna, Italy
(2) DTA-LETI-DEIN-SPE, CEA Saclay, France
(3) Department of Physics, The University of Sheffield, UK
(4) Laboratoire des Matériaux Moléculaires, CNRS Thiais,
France
(5) IWV-3, Forschungszentrum Juelich, Germany
Metal Cluster Enhanced Organic Solar Cells
Michael Westphalen (1), Uwe Kreibig (2), Jörn Rostalski (1), Hans
Lüth (3), Dieter Meissner (1)
(1) IWV-3, Forschungszentrum Juelich, Germany
(2) Department of Physics, RWTH Aachen, Germany
(3) ISI, Forschungszentrum Juelich, Germany
Monochromatic versus Solar Efficiencies of Organic Solar Cells
Jörn Rostalski, Dieter Meissner
IWV-3, Forschungszentrum Juelich, Germany
Water Influence on Molecular Organic Solar Cells
Thomas Haueisen, Jörn Rostalski, Dieter Meissner
IWV-3, Forschungszentrum Juelich, Germany
Photoelectric Conversion Using Titanyl Phthalocyanine
Toshimitsu Tsuzuki, Naoki Noma, and Yasuhiko Shirota
Department of Applied Chemistry, Faculty of Engineering, Osaka University,
Japan
Electrophotography, Commercial Application of Organic Materials in Electrooptic
Devices
Manfred Lutz
AEG - Elektrofotografie GmbH, Warstein, Germany
Photoinduced FTIR spectroscopy and CW-Photocurrent Measurements of
Conjugated Polymers and Fullerenes Blended into a Conventional Polymer
Matrix
Christoph J. Brabec (1), H. Johannson (1), F. Padinger (1), Helmut
Neugebauer (1), Jan C. Hummelen (2), N. Serdar Sariciftci (1)
(1) CD Laboratory for Plastic Solar Cells, J. Kepler University, Linz, Austria
(2) Org. and Molec. Inorg Chemistry, University of Groningen, The Netherlands
Stability Studies and Analysis of Degradation Mechanisms of Conjugated
Polymer / Fullerene Plastic Solar Cell Components
Helmut Neugebauer, Christoph J. Brabec, N. Serdar Sariciftci
CD Laboratory for Plastic Solar Cells, J. Kepler University, Linz, Austria
Characterization of Photovoltaic Devices Based on Para-Hexaphenyl / C60
Bilayers
Gebhard Matt (1), Christoph J. Brabec (1), Helmut Neugebauer (1), Helmut
Sitter (2) and N. Serdar Sariciftci (1)
(1) CD Laboratory for Plastic Solar Cells, J. Kepler University, Linz, Austria
(2) Inst. of Semiconductor Physics, J. Kepler University, Linz, Austria
Electric Fields in Molecular Organic Solar Cells Investigated by
Electroabsorption Spectroscopy
P. Lane (1), J. Rostalski (2), D. Bradley (1), D. Meissner (2)
(1) Department of Physics, The University of Sheffield, UK
(2) IWV-3, Forschungszentrum Juelich, Germany
Influence of molecular orientation on the photovoltaic behavior of
oligothiophenes
Christine Videlot and Denis Fichou
Laboratoire des Matériaux Moléculaires, CNRS Thiais, France
Organic solar cells based on rare earth bisphtalocyanine complexes
Christine Videlot, Denis Fichou and Francis Garnier
Laboratoire des Matériaux Moléculaires, CNRS Thiais, France
Nanoscale photovoltaics on organic single crystals
S. Quemener, Fabrice Charra, Denis Fichou, and A. Gusev
Laboratoire des Matériaux Moléculaires, CNRS Thiais, France
Dye sensitized polythiophene solar cells
Lionel Sicot, Céline Fiorini, André Lorin, Jean-Michel Nunzi, Paul
Raimond and Carole Sentein
DTA-LETI-DEIN-SPE, CEA Saclay, France
Orientation induced molecular rectification in polymer films: improvement
of organic-semiconductor devices efficiency
Carole Sentein, Céline Fiorini, André Lorin, Jean-Michel
Nunzi, Paul Raimond, Lionel Sicot
DTA-LETI-DEIN-SPE, CEA Saclay, France
Chemical aspects of plastic solar cells
Joop Knol, Bea M.W. Langeveld-Voss, Rene A.J. Janssen, and Jan C.Hummelen
Org. and Molec. Inorg Chemistry, University of Groningen, The Netherlands
Photovoltaic Cells of Polycyclic Aromatic Semiconductors
Dieter Wöhrle, S. Hiller, N. Trombach
Institute for Org. and Macromolecular Chemistry, University of Bremen,
Germany
Photovoltaic Properties of Organic Materials
Yasuhiko Shirota
Dept. of Applied Chemistry, Fac. of Engineering, Osaka University, Japan
Conjugated Polymer Based Photovoltaic Devices
Christoph Brabec (1), Jan Kees Hummelen (2) and N. Serdar Sariciftci (1)
(1) CD Laboratory for Plastic Solar Cells, J. Kepler University, Linz, Austria
(2) Org. and Molec. Inorg Chemistry, University of Groningen, The Netherlands
Dye Sensitized Solar Cells: Development and Prospects
Klaus Peter Hanke
Institut für Angewandte Photovoltaik GmbH (INAP), Gelsenkirchen,
Germany
Design of Photoactive Molecular Devices Based on Quantum Chemical
Investigations of Phenylenediamine, Carbazole, Tetracianoquinodimethane and
Benzene Molecules
Jelena Tamuliene, Arvydas Tamulis, Mindaugas L. Balevicius, Nick A. Kotov
(1) Inst. of Theoretical Physics and Astronomy, Vilnius, Lithuania
(2) Faculty of Physics, Vilnius University, Lithuania
(3) Department of Chemistry, Oklahoma State University, Stillwater,
Oklahoma, USA
Dye-Sensitized Solid State Photovoltaic cell with Novel Organic Hole Transport
Materials
M. Thelakkat, J. Hagen, M. Denzler and D. Haarer
Makromolekulare Chemie I, University of Bayreuth, Germany
INAP-Poster 1
Klaus Peter Hanke
Institut für Angewandte Photovoltaik GmbH (INAP), Gelsenkirchen,
Germany
INAP-Poster 2
Klaus Peter Hanke
Institut für Angewandte Photovoltaik GmbH (INAP), Gelsenkirchen,
Germany
On the Origin of Limited Photocurrent Efficiencies in Molecular Organic Solar
Cells
Jörn Rostalski, Stefan Günster, Andreas Bertram, Dieter Meissner
IWV-3, Forschungszentrum Juelich, Germany
Photoelectric Conversion Using Titanyl Phthalocyanine
Yasuhiko Shirota
Dept. of Applied Chemistry, Fac. of Engineering, Osaka University, Japan
Morphology of Thin Film Organic Semiconductors for Solar Cell Applications
Renate Hiesgen (1), Dieter Meissner (2)
(1) Physics Department E19, Technische Universität München, Germany
(2) IWV-3, Forschungszentrum Juelich, Germany
Sensitizing organic solar cells with organized dye layers
Rob B. Koehorst, Huub Maas, Tjeerd J. Schaafsma
Dpt. of Biomolecular Sciences, Wageningen Agricultural University,
The Netherlands
Polymer Structural Modification Effects on Organic Conducting Polymer-Inorganic
Semiconductor Photovoltaic Junctions
Hoan Nguyen Cong (1), Cheikh Sène (2), Moustapha Dieng (2), Pierre
Chartier (1)
(1) Faculté de Chimie, Université Louis Pasteur, Strasbourg,
France
(2) Département de Physique, Université Cheikh Anta Diop,
Dakar-Fann, Sénégal
Tetracyanoanthraquinodimethane (TCAQ) and TCAQ-C60 Derivatives as Electron
Acceptors in Photoinduced Electron Transfer Systems
Rafael Gomez, Nazario Martin and Jose L. Segura
Dpto. de Qimica Organica, Facultad de Qimica, Universidad Complutense,
Spain
Limits to Energy Conversion Efficiency for Polymer Photovoltaic cells based on
photoinduced charge transfer between donor-acceptor molecules
D. Godovsky, O. Inganäs
IFM, Linköping University, Linköping, Sweden
Directed Interconnected Networks for Organic Photovoltaic Cells
Klaus Kohrs
Schweinitz, Germany